I saw this recipe on food gawker. It caught my attention because my chive plant was is bloom. I never thought of using the flower for anything. Once I picked them, I smelled them and they had a distinctive chive smell!
The recipe says just put them into vinegar  in a jar and shake everyday. Eventually discard the blossoms. 
The recipe said you could use whatever vinegar you prefer. I just used some extra plain white vinegar I had in the cupboard and threw it into an old jelly jar. 
Here is the results after a few days.  
The vinegar takes on a light pink hue.  Think I will let it brew a bit longer.  The recipe suggested using the vinegar for salad dressings.  




 
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